What is a Chemical Weapon?

A Chemical Weapon is a chemical used to cause intentional death or harm through its toxic properties. Munitions, devices and other equipment specifically designed to weaponise toxic chemicals also fall under the definition of chemical weapons.

 

A common conception of a chemical weapon (CW) is of a toxic chemical contained in a delivery system such as a bomb or artillery shell. While technically correct, a definition based on this conception would only cover a small portion of the range of things the Chemical Weapons Convention (CWC) prohibits as ‘chemical weapons’.

Under the CWC, the definition of a chemical weapon includes all toxic chemicals and their precursors, except when used for purposes permitted by the Convention – in quantities consistent with such a purpose.

CW Definition in Three Parts

chemicals

Toxic chemicals and their precursors

Toxic chemicals are defined as ‘any chemical which through its chemical action on life processes can cause death, temporary incapacitation or permanent harm to humans or animals’. 

This includes all such chemicals, regardless of their origin or of their method of production, and regardless of whether they are produced in facilities, in munitions or elsewhere.

Precursors are chemicals that are used for the production of toxic chemicals.

Munitions

Munitions or devices

Any munitions or devices specifically designed to inflict harm or cause death through the release of toxic chemicals.

Among these could be mortars, artillery shells, missiles, bombs, mines or spray tanks.

equipment

Equipment ‘directly in connection’ with munitions and devices

Any equipment specifically designed for use ‘directly in connection’ with the employment of the munitions and devices identified as chemical weapons.

Examples of CWs include, but are not limited to:

  • Fully developed chemical weapons and the components of such weapons when stored separately (e.g. binary munitions).
  • Chemicals used to produce chemical weapons (precursors).
  • Chemicals used to cause intentional death or harm.
  • Items with peaceful civilian uses, when used or intended for chemical weapons use (dual-use items).
  • Munitions and devices intended for the delivery of toxic chemicals.
  • Equipment directly in connection with aforementioned munitions and devices.

The full and legal definition of a Chemical Weapon can be found in Article II of the Chemical Weapons Convention.

General Purpose Criterion – Intent

A toxic or precursor chemical may be defined as a chemical weapon depending on its intended purpose.

A toxic or precursor chemical is defined as a chemical weapon unless it has been developed, produced, stockpiled or used for purposes not prohibited by the Convention.

Any chemical intended for chemical weapons purposes, regardless of whether it is specifically listed in the Convention or its Annexes (including the three schedules of chemicals) is considered a chemical weapon.

The CWC does not expressly state what ‘chemical weapons purposes’ are. Rather, it defines purposes that are not prohibited by the Convention.

Principle of Consistency

A toxic chemical held by a State Party in agreement with the “Principle of Consistency” must be produced, stockpiled or used for a legitimate purpose, and be of a type and quantity appropriate for its “peaceful” purpose.

Definitions Related to the CWC

Riot Control Agents (RCAs)

A riot control agent is defined as any chemical not listed in a schedule which can produce sensory irritation or disabling physical effects rapidly in humans and which disappear within a short time following termination or exposure.

The use of riot control agents as a method of warfare is prohibited by the CWC.

Chemical Weapon Components

The Convention defines each component of a chemical weapon as a chemical weapon — whether assembled or not, stored together or separately.

A toxic chemical and delivery system, for example, may be stored separately, each in and of itself less than a fully developed weapon — but each are still considered chemical weapons under the Convention.

Precursor

Any chemical reactant which takes part, at any stage and by whatever method, in in the production of a toxic chemical. This includes any key component of a binary or multicomponent chemical system.

For the purpose of implementing this Convention, precursors which have been identified for the application of verification measures are listed in Schedules contained in the Annex on Chemicals.

Dual-Use

Dual-use describes chemicals or equipment that can be used for peaceful civilian and commercial purposes, but can also be used in the creation of weapons or as weapons.

Herbicides

The prohibition of the use of herbicides as a method of warfare is recognised in the CWC Preamble. However, herbicides are not defined specifically in the Convention.

Herbicides that are intentionally used to harm humans or animals through chemical action on life processes could be considered a chemical weapon under the general purpose criteria.”

 

Central Nervous System (CNS) – Acting Chemicals

Central Nervous System acting chemicals, which are sometimes referred to as incapacitating Chemical Agents (ICAs), are not defined or mentioned by name in the Convention. The Convention does refer to toxic chemicals that can cause, inter alia, ‘temporary incapacitation’.

The general purpose criterion still holds to the extent that chemicals considered CNS-acting meet the definition of toxic chemicals.

Depiction of the soman conjugate of acetylcholinesterase

Depiction of the soman conjugate of acetylcholinesterase. Nerve agents like soman inhibit the normal actions of acetylcholinesterase, an enzyme crucial to nervous systems (Protein Data Bank Structure 2WFZ)

 

 

Toxins

Toxins are toxic chemicals produced by living organisms. These are considered as both chemical and biological weapons when used in violation of the Convention.

 

Toxins are toxic chemicals produced by living organisms. These are considered as both chemical and biological weapons when used in violation of the Convention.

The development, production and stockpiling of toxins for purposes of warfare are prohibited under both the CWC and Biological Weapons Convention (BWC). Like the CWC, the BWC also requires States parties that possess toxin weapons to destroy them.

Toxins are covered by the CWC because they are chemicals that can have chemical weapons applications, and fall under the definitions listed above for chemical weapons and toxic chemicals.

Synthetic Toxins

It is possible to synthesis many types of toxins in laboratories without harvesting the organisms that produce them in nature. Moreover, a number of toxins are also synthetic dual-use chemicals, meaning that under the CWC they can be produced in the quantities required for legitimate activities.

There are two toxins explicitly listed in Schedule 1, these are ricin (produced in nature in the seeds of the castor bean plant) and saxitoxin (produced in nature by cyanobacteria).

Old and Abandoned Chemical Weapons

Old chemical weapons fall into two categories: chemical weapons produced before 1925 and chemical weapons produced between 1925 and 1946 ‘that have deteriorated to such an extent that they can no longer be used as chemical weapons’.

Old chemical weapons of the first category may be ‘destroyed or disposed of’ as toxic waste in accordance with the relevant State Party’s national laws after the OPCW Secretariat has confirmed that they were indeed produced before 1925.

Those weapons that fall into the second category of old chemical weapons are to be destroyed in accordance with the same conditions as other chemical weapons, though the time limits and the order of destruction can be changed, subject to approval by the Executive Council.

Guidelines for determining whether weapons in this category have deteriorated enough to be unusable, however, have yet to be decided, though efforts to do so are ongoing. Categorisation of such weapons therefore remains problematic.

Abandoned Chemical Weapons are chemical weapons, including old chemical weapons, abandoned by a State after 1 January 1925 on the territory of another State without the consent of the latter.

Verifying Destruction of Old and Abandoned Chemical Weapons

 Types of Chemical Agents

Lungs

Choking agents

Inflicting injury mainly on the respiratory tract, choking agents irritate the nose, throat, and especially the lungs. When inhaled, these agents cause alveoli, air sacs in the lungs, to secrete fluid, essentially drowning those affected 

Example agents

  • Chlorine (Cl)
  • Chloropicrin (CG)
  • Diphosgene (DP)
  • Phosgene (PS)

Dispersal
Gas

Mode of Action
Absorption through lungs

Effects
Fluid builds up in lungs, choking victim

Skin of Human Body

Blister agents

One of the most common chemical weapon agents, these oily substances act via inhalation and contact, affecting the eyes, respiratory tract, and skin, first as an irritant and then as a cell poison. Exposure to blister agents cause large and often life-threatening skin blisters which resemble severe burns, and often results in blindness and permanent damage to the respiratory system.
Although casualties are high, deaths represent a small percentage.

Example Agents

  • sulfur mustard (H, HD)
  • nitrogen mustard (HN)
  • lewisite (L) and phosgene oxime (CX)

Dispersal
Liquid, aerosol, vapour, and dust

Mode of Action
Absorption through lungs, skin

Effects
Burns skin, mucous membranes and eyes; blisters skin, windpipe, and lungs

Blood vessels of human body

Blood agents

These agents cause the body to suffocate by inhibiting the ability of blood cells to use and transfer oxygen, effectively causing the body to suffocate. Blood agents are distributed via the blood and generally enter the body through inhalation.

Example agents

  • Hydrogen cyanide (AC)
  • Cyanogen chloride (CK)
  • Arsine (SA)

Dispersal
Gas

Mode of Action
Absorption through lungs

Effects
Blood cells’ ability to use oxygen inhibited

Nerves in Human Body

Nerve agents

Nerve agents block impulses between nerve cells or across synapses and are highly toxic with rapid effects. They act primarily by absorption through the skin and lungs. Nerve agents are divided into two main groups: G-series agents and V-series agents, named for their military designations. Some G-agents, particularly tabun and sarin, persist in the environment for only short periods. Other agents, such as soman and cyclosarin, persist longer and present a greater threat to the skin. V-agents are extremely potent, with only milligrams needed to cause death, and persist for long periods of time in the environment.

Example agents

  • Tabun (GA)
  • Sarin (GB)
  • Soman (GD)
  • Cyclosarin (GF)
  • VX

Dispersal
Liquid, aerosol, vapour and dust

Mode of Action
Absorption through lungs (G-series); contact with skin (VX)

Effects
Causes seizures, loss of body control; paralyses muscles, including heart and diaphragm

Mouth, Throat and Lungs

Riot control agents

Riot control agents are intended to temporarily incapacitate a person by causing irritation to the eyes, mouth, throat, lungs, and skin.

Riot control agents, such as tear gas, are considered chemical weapons if used as a method of warfare. States can legitimately possess riot control agents and use them for domestic law enforcement purposes, but states that are members of the Chemical Weapons Convention must declare what type of riot agents they possess.

Example agents

  • Tear Gas (CS)
  • Pepper Spray (OC)

Dispersal
Liquid, aerosol

Mode of Action
Absorption through lungs, skin and eyes

Effects
Tears, coughing, and irritation to eyes, nose, mouth and skin; constricts airway

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